Structural Properties of Some Cyanoethenes with Optical Nonlinearity

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概要

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• An α-cyanostilbene crystal showing optical nonlinearity was examined to be compared with a non-optically active crystal, with emphasis on the structural aspect. It was suggested that the introduction of bulky substituents such dimethylamino and methoxy groups into the cyanostyrene conjugation system was effective to get macroscopic optical nonlinearity, based on the chemical synthesis and structural analysis. It was also stressed that the quadrupole interaction in α-cyanostilbenes was one of the important factors responsible for a nonsymmetric molecular arrangement for the second order optical nonlinearity.

• 社団法人応用物理学会の論文
• 1994-10-15

著者

• GOTOH Masahide

  The Institute of Scientific and Industrial Research, Osaka University

• Yano Seiki

  Functional Devices Laboratories Sharp Corporation

• Arai H

  Tokyo Metropolitan Univ. Tokyo Jpn

• Gotoh Midori

  The Institute Of Scientific And Industrial Research Osaka University

• ARAI Hisako

  Functional Devices Laboratories, Sharp Corporation

• HIGASHIGAKI Yoshiyuki

  Central Research Laboratories, Sharp Corporation

• GOTOH Midori

  National Institute of Materials and Chemical Research

• Gotoh Midori

  National Institute Of Advanced Industrial Science And Technology (aist)

• Higashigaki Y

  Central Research Laboratories Sharp Corporation

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