Structual Studies of Poly(Fluoroalkyl Methacrylate)s and Poly(Fluoroalkyl α-Fluoroacrylate)s
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概要
- 論文の詳細を見る
Poly(fluoroalkyl methacrylate)s and poly(fluoroalkyl α-fluoroacrylate)s with various fluoroalkyl groups were prepared. These polymers were characterized for tacticity by proton and fluorine nuclear magnetic resonance (^1H and ^<19>F NMR) and investigated by Electron Spectroscopy for Chemical Analysis (ESCA) to assign each signal. We found that tacticity of poly(fluoroalkyl α-fluoroacrylate)s were independent of the fluoroalkyl structure. The relationship between the structure of polymers and ESCA signals for all polymers was clarified. Also, we found an orientation effect of fluoroalkyl groups on the surface of the polymer films through the analysis of F1s ESCA signals.
- 社団法人応用物理学会の論文
- 1992-10-15
著者
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OHMORI Akira
Osaka University
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IWAMI Motohiro
Research Laboratory for Surface Science, Faculty of Science, Okayama University
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Ohmori A
Osaka Univ. Osaka Jpn
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Iwami Motohiro
Reseach Laboratory For Surface Science Faculty Of Science Okayama University
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Iwami M
Department Of Physics Faculty Of Science Hiroshima University
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Shimizu Tetuo
Daikin Industries Ltd.
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KOIZUMI Shun
MITSUBOSHI Co., Ltd.
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OHMORI Akira
DAIKIN Industries Ltd.
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Ohmori A
National Institute For Materials Science
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Koizumi Shun
Mitsuboshi Co. Ltd.
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