Temperature Dependence of the Delayed Fluorescence Lifetime in Anthracene Crystals with Triplet Exciton Traps

概要

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The lifetime of delayed fluorescence of anthracene crystals excited by the chopped-light of a He-Ne laser is investigated as a function of temperature over the range 110-480 K. As compared with the fluorescence intensity, the lifetime is not influenced much by the temperature dependence of triplet-triplet annihilation rate and singlet-triplet absorption coefficient. Considering a trap saturation effect, an analysis has been made of the temperature dependence of the lifetime. In defect-induced crystals, three kinds of defects are observed by X-ray irradiation. Two are 0.33 and 0.16 eV in triplet trap depth, and the trapped triplet decay rate is 〜5×10^6 s^<-1> for both; the other is 0.29 eV and 〜1 s^<-1>. The latter is of a different type from the former, namely, it is almost a pure trapping center which hardly quenches triplet excitons.
社団法人応用物理学会の論文
1980-09-05