SOLID SOLUTIONS OF BE, AL-MORDENITES

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概要

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• The solid solution between beryllosilicate and aluminosilicate mordenites was synthesized at 423K, and the Be end-member has BeO/(Al_2O_3+BeO) mole fraction of 0.75 because of the contamination of impurity alumina in the silica source. The lattice constants a, b and c of the solid solution decrease with the replacement of Al by Be atoms, and are 1.808,2.044 and 0.750nm for the Al end-member and 1.803,2.027 and 0.744nm for the Be end-member. However, the existence of a continuous solid solution between 0.4 and 0.5 for BeO/(Al_2O_3+BeO) mole fraction of product is somewhat uncertain. A part of benzyltrimethylammonium base in the structure of the solid solution plays a role of cations to neutralize negative framework charge, and the remainder is supposed to be present as a molecule.

• 日本粘土学会の論文

著者

• Yamada Hirokazu

  Institute Of Biological Sciences University Of Tsukuba

• Yamada Hirokazu

  Institute Of Scientific And Industrial Research Osaka University

• Yamada Hirohisa

  National Institute For Research In Inorganic Materials

• KOIZUMI Mitsue

  Institute for Scientific and Industrial Research,Osaka University

• Koizumi M

  Osaka Univ. Ibaraki Jpn

• Ueda S

  Osaka Univ. Ibaraki Jpn

• UEDA SATORU

  Institute of Scientific and Industrial Research, Osaka University

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