HYBRIDIZATION OF CLAY NANOSHEETS IN POLY(ETHYLENE TEREPHTHALATES)

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概要

• 論文の詳細を見る

• The hybridization of poly(ethylene terephthalate) (PET) with montmorillonite (Mont) clay was investigated using anchor monomers, i,e., hydroxyethyl isonicotinamide (HENA) or hydroxypentyl-trimethylammonium iodide (HPTA), which have cationic substituents to adsorb onto clay surfaces and a hydroxyethyl moiety (-CH_2CH_2OH) to react with the polymer chain terminal of PET. The condensation of the mixtures of the intercalation compounds, bis (2-hydroxyethyl) terephthalate (BHET) and HENA/ Mont or HPTA/Mont, led to a homogenous and transparent PET hybrid in which the Mont clay particles were scattered homogenously. The HPTA/Mont hybrid films copolymerized with BHET exhibited a dramatic improvement in such characteristics as tensile strength and optical transparency.

• 日本粘土学会の論文

著者

• SHICHI Tetsuya

  Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University

• Shichi T

  Nagoya Univ. Nagoya

• Shichi Tetsuya

  Department Of Crystalline Materials Science Faculty Of Engineering Nagoya University

• Zhang Guozhen

  Department Of Crystalline Materials Science Graduate School Of Engineering Nagoya University

• Zhang Guozhen

  Department Of Applied Chemistry Graduate Course Of Engineering Tokyo Metropolitan University

• TONG Zhiwei

  Department of Applied Chemistry, Graduate Course of Engineering, Tokyo Metropolitan University

• Tong Z

  Department Of Crystalline Materials Science Graduate School Of Engineering Nagoya University

• TAKAGI KATSUHIKO

  CREST, JST(Japan Science and Technology)

• Takagi Katsuhiko

  Crest Jst(japan Science And Technology)

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