水質汚濁指標に関する研究(第8報)二価脂肪酸, 不飽和脂肪酸のCOD_<Mn>について

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COD values (with permanganate) of dicarboxylic acids and unsaturated acids were investigated by the micro titration method previously reported. Dicarboxylic acids will be contained in various industrial effluents and produced during the COD treatment of unsaturated acids. Unsaturated carboxylic acids are constituents of oils extracted from plants or fishes and contained in the domestic effluents. In the case of dicarboxylic acids having longer carbon chain, marked promotion effects of AgNO_3 added into a reaction medium on the COD values were recognized. Average oxydation rate to the perfect oxydation was 12.4%. In alkaline method, oxydation rate was very low values of 0.636%. Oxydation rate by BOD determination was very high rate of 72.1%. In the case of unsaturated acids, the COD values were corresponded to the numbers of unsaturated bonds. Oxydation rate was 39.3% in the acidic and 31.8% in the alkaline method. Determination of reaction products will be reported in the latter.
社団法人日本薬学会の論文
1989-02-28