二酸化窒素が関与する環境中での光化学反応 : グリオキサール類, ニトロフェノール類及びエポキシドの空気中での生成
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概要
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Nitrogen dioxide is known to be an air pollutant inducing photochemical smog, in which reactive species such as an oxygen atom O (^3P), ozone and hydroxyl radical etc. could take part in its appearance. Aromatic hydrocarbons released from automobiles into the troposphere underwent a ring fission leading to glyoxals (α-diketones) and the hydroxyl-nitration of the ring leading to nitrophenols under the circumstances. Their formation could be attributed to the action of the above active species. Moreover, α-diketones or suspended particulates, one of air pollutants, caused the photo-epoxidation, for example, converting aldrin into the corresponding epoxide, dieldrin.
- 公益社団法人日本薬学会の論文
- 1995-04-30
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