Decomposition of Dithiocarbamates. IX. The Effect of Carbon Disulfide on the Decomposition of N-Monosubstituted Dithiocarbamic Acids

概要

論文の詳細を見る
The effect of carbon disulfide on the decomposition of N-monosubstituted dithiocarbamic acids was kinetically investigated. In the preparation of I, the presence of excess of carbon disulfide was elucidated to accelerate the decomposition of I. The rate is proportional to [CS_2], [OH^-] and [I], respectively. This is explained by the pathway, I⇌II⇌^^^<CS_2>VIII→^^^<OH^->VI ; carbon disulfide reacts with I to afford an adduct VIII, which plays an important role. The requirement of pH-control for preparation of I was interpreted by the results.
公益社団法人日本薬学会の論文
1974-02-25