Photochemistry of Succinimides with a Cycloalkenylalkyl Group in the Side Chain. Competitive Norrish Type II and Paterno-Buchi Reactions

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概要

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• Photolysis of N-[ω-(cycloalken-1-yl) alkyl] succinimides (9c-f) (m≨2) afforded mainly azepinediones (13c-f) with ring enlargement as the Norrish type II cyclization products. In the case of m=1,spiro-azepinedione derivatives (11a, b) were obtained in addition to tricyclic nitrogen heterocycles (10a, b), the Norrish type II products. These spiro-azepinediones are probably formed via imide-oxetanes by the intramolecular Paterno-Buchi reaction of these succinimides in competition with the type II processes.

• 公益社団法人日本薬学会の論文
• 1984-03-25

著者

• 町田 實

  北海道医療大学歯学部

• 金岡 裕一

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 町田 實

  Faculty of Pharmaceutical Sciences, Higashi Nippon Gakuen University

• 町田 實

  Faculty Of Pharmaceutical Sciences Higashi-nippon-gakuen University

• 小田 和明

  Faculty of Pharmaceutical Sciences, Higashi-Nippon-Gakuen University

• 小田 和明

  北海道医療大学歯学部

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