Absorption Spectral Shift of meso-Tetraphenylpor-phinatocadmium on Axial Ligation
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概要
- 論文の詳細を見る
The effects of axial ligation to meso-tetraphenylporphinatocadmium (CdTPP) were studied in dimethyl sulfoxide (DMSO) or dichloromethane (CH_2Cl_2). Addition of neutral (L) or anionic ligands (X-) to CdTPP caused red shifts in the absorption spectrum. The magnitude of the red shift depended on the charge but not on the strength of the Cdligand bond. Further, a relationship between the ratio ε_α/ε_β and the wavenumber of the Soret band was observed.
- 公益社団法人日本薬学会の論文
- 1983-06-25
著者
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小沢 俊彦
放射線医学総合研究所
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花木 昭
National Institute of Radiological Sciences
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花木 昭
Faculty Of Engineering Shizuoka University
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Hanaki A
Faculty Of Engineering Shizuoka University
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小沢 俊彦
National Institute of Radiological Sciences
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