Studies on Cholestapolyenes. VI. 3-Cyclohexylcholestane and its Derivatives.
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概要
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3β-Cyclohexylcholestane was prepared from cholest-5-ene-3β-carboxylic acid and the fact is that the carbanion formed in the Grignard reagent of 3β-chlorocholest-5-ene was β-oriented in reaction with cholestan-3-one, i.e. the conformation at 3-position is retained. Discussions were also made on the structure of 3β-cyclohexylcholestan-3α-ol and 3-cyclohexylcholest-2-ene.
- 公益社団法人日本薬学会の論文
- 1958-06-20
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関連論文
- Studies on Cholestapolyenes. I. : Syntheses of Bicholestatriene A and 7-Dehydrocholesterol.
- Studies on Cholestapolyenes. VIII. Separation of Stereoisomers of Bicholestane.
- Studies on Cholestapolyenes. VII. Bicholestane and its Derivatives.
- Studies on Cholestapolyenes. VI. 3-Cyclohexylcholestane and its Derivatives.