Quinol類に関する知見(第3報)2-Oxo-8,10-dihydroxy-△^<1,9;3,4>-hexahydronaphthy1-7-acetic Acid Lactoneの転位
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概要
- 論文の詳細を見る
2-Oxo-8,10-dihydroxy-△^<1,9;3,4>-hexahydronaphthy1-7-acetic acid lactone underwent rearrangement to 2,4,8- and 1,4,8-trihydroxytetrahydronaphthy1-7-acetic acid lactone by dilute sulfuric acid, and to 2,4-diacetoxy-8-hydroxytetrahydronaphthy1-7-acetic acid lactone by acetic anhydride and sulfuric acid. It was concluded that when hydroquinone rearrangement was hindered a resorcinol rearrangement might take place instead of catechol rearrangement. A synthesis of 1,4,8-trihydroxytetrahydronaphthty1-7-acetic acid lactone was also described.
- 公益社団法人日本薬学会の論文
- 1955-10-20
著者
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百瀬 勉
Pharmaceutical Institute, Medical Faculty, University of Kyushu
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百瀬 勉
Pharmaceutical Institute Medical Faculty University Of Kyushu
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三木 卓一
Department Of Toxicology Faculty Of Pharmaceutical Sciences Setsunan University
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三木 卓一
Pharmaceutical Institute, Medical Faculty, University of Kyushu
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沢田 啓
Pharmaceutical Institute, Medical Faculty, University of Kyushu
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三木 卓一
Research Laboratory Takeda Pharmaceutical Industries Ltd.
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沢田 啓
Pharmaceutical Institute Medical Faculty University Of Kyushu
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