2-ヒドロキシフェニルアゾメチン及び2,2′-ジヒドロキシアゾベンゼン誘導体のガリウム及びアルミニウムキレートの物理化学的性質と蛍光強度との関係 : 蛍光強度に与える置換基の效果(第二報)

概要

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Several 2-hydroxyphenylazomethine and 2,2′-dihydroxyazobenzene derivatives were prepared and the effect of the physico-chemical properties of substituent groups on the fluorescence intensity of aluminium and gallium chelates were investigated. The utilized regression analysis is the same technique used in Hansch-Fujita's method, an analytical technique known to describe quantitatively the structure-activity relationships (QSAR) of a series of chemical analogs. Using the partition coefficient log P and Hammett constant σ as parameters, fairly good correlations were observed for the fluorescence intensities of the test compounds. It is suggested that the technique could be applicable to the quantitative analysis of derivatives having the same basic structure as well as structure-biological activity relationships.
社団法人日本分析化学会の論文
1991-09-05