Glucopyranosidic PolymerのPaper Chromatography : (其の1) 化學構造と呈色反應との關連性について : 非醗酵性糖に關する研究 (第13報)

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Using several spray reagents (aniline hydrogen phthalate, anisidine phosphate, benzidine trichloride, aniline hydrochloride, 3,5-dinitrosalicylate and silver nitrate), the relation between the color reaction and the structure of the gluco-bioses containing different linkages was tested on paper chromatograms (Table 2). The developing time and color character of spots by each reagent were found to be helpful for the determination of the chemical structures.The color difference depending on such linkages as 1,2,1,3-, 1,4- and 1,6- was more distinctive than the difference between α-and β-linkages. Among the above reagents, aniline hydrogen phthalate and aniline hydrochloride were the most useful. We shall be able to distinguish the structure of all gluco-bioses and a moreover glucose-polymers from the obtained results together with the Rf value or the action of glucosidase.
社団法人日本生物工学会の論文
1955-03-15