不定比化合物V_2O_<3+x>の研究
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概要
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Magnetic susceptibility, density and lattice constant of V_2O_<3+x> fired at 1600゜K and 1700゜K were measured. When x (in V_2O_<3+x>) reaches to 0.03, a discontinuity was found in the curve of susceptibility vs. nonstoichiometric parameter x. The similar discontinuity was also found in the density curve at x≃0.04. At x≃0.05 an abrupt change in the lattice constant was detected. Magnetic susceptibility measurement seems to be the most sensitive method for detecting nonstoichiometry in the V_2O_<3+x> compound.
- 社団法人日本セラミックス協会の論文
- 1973-04-01