Microwave Spectrum of Hydrazine-1,2-d_2
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The microwave spectrum of deuterated hydrazine has investigated in the frequency range of 8-105 GHz. There are three species for hydrazine-1, 2-d_2 and the rotational constants are determined to be A=102309.0 MHz, B=21306.7 MHz and C=20356.5 MHz, A=100173.8 MHz, B=20930.5 MHz and C=20843.6 MHz and A=98246.3 MHz, B=21529.1 MHz and C=20404.8 MHz. From the Stark effect of low-J lines the dipole moment is found to be 1.90 D. the structural parameters of hysrazine are obtained using the rotational constants of deuterated species to be N-H=1.008±0.008Å, N-N=1.447±0.005Å, ∠HNH=113°16'±3°, ∠NNH=109°09'±50' and dihedral angle between the two amino groups=88°55'±1.5°.
- 社団法人日本物理学会の論文
- 1976-12-15
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