Polarization Power Parameter in Binary Fused Salt Systems

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概要

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• In order to show the limit of the congruently melting compound formation in binary fused salt systems introduction of a parameter is proposed in this paper. The parameter is defined by I_1=n_1P_1/(n_1P_1+n_2P_2) where P_i and n_i are the polarization power of cation (P_1>P_2) and the mole fraction of the i-th salt respectively. When the congruently melting compound is formed in the binary system of alkali chlorides the values of I_1 are found to fall into the range 0.5-0.95. Further, a linear relation is found between the equivalent conductivity of the binary fused salt system and the parameter I_1. A discontinuous change in the slope is observed at the point where the congruently melting compound is formed.

• 社団法人日本物理学会の論文
• 1973-10-05

著者

• OYAMADA Ryozo

  National Research Institute for Metals

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• The Limiting Temperature of Solid-Like Structure
• Effective Mass of Ions in Fused Salts

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