ESR _g Factors of Isolated (TMTSF)^+ and (TMTSF)_2ClO_4 Single Crystals:Comparison with Molecular Orbital Calculation
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概要
- 論文の詳細を見る
Measurements and comparisons were performed at 4.2 K on the ESR g tensorboth of a single crystal of bis-(tetramethyltetraselenafulvalenium) perchlorate,(TMTSF).Cl0., and its acetone solution in which cations exist in the form ofTMTSF". The results showed that there was no wide difference between the ganisotropy of the single crystal and solution. This fact suggests that the electronicstates of (TMTSF)" can be used as a substitute for (TMTSF).CI0. as long as gfactors are concerned. The g factors, calculated from molecular orbitals (MO)of a TSF" cation which were computed using semi-empirical SCF method, werethen fitted to those of the single crystal, and z-electron distribution was decidedfrom the highest occupied MO.
- 社団法人日本物理学会の論文
- 1984-04-15
著者
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ANZAI Hiroyuki
Electrotechnical Laboratory
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ISHIGURO Takehiko
Electrotechnical Laboratory
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SAITO Gunzi
Institute for Solid State Physics,The University of Tokyo
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TOKUMOTO Madoka
Electrotechnical Laboratory
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KINOSHITA Nobumori
Electrotechnical Laboratory
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Yamabe Tokio
Kyoto University
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ANZAI Hiroyuki
Department of Material Science, Himeji Institute of Technology
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Anzai H
Himeji Inst. Technol. Kamigohri Jpn
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Anzai Hiroyuki
Electrotechnical Laboratory Umezono
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Saito Gunji
Department Of Chemistry Kyoto University
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TERAMAE Hiroyuki
Kyoto University
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Ishiguro Takehiko
Electrotechincal Laboratory
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Kinoshita N
Electrotechnical Laboratory
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Saito G
Department Of Chemistry Kyoto University
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Saito Gunzi
Institute For Molecular Science:institute For Solid State Physics University Of Tokyo
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Ishiguro T
Nagaoka Univ. Technol. Nagaoka Jpn
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Anzai Hiroyuki
Electrotechmical Laboratory
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SAITO Gunzi
Institute for Molecular Science
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Tokumoto Madoka
Electronics and Photonics Research Institute (EPRI), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568, Japan
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