Theory of Pressure-Induced Staging Transitions in Graphite Intercalation Compounds
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概要
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Theory is presented of the mechanism of pressure-induced staging transitionsin alkali-metal graphite intercaJation compounds (A-GIC's). The most stablestoichiometrv at 7": 0 K is determined for various srecies of intercalant atoms.Effect of pressure is taken into account by varying the distance between the twographite layers which sandwich an intercalant layer. Lithium G[C's are foundto be stable with the stoichiometry of LiC..., where n is the stage number, atall pressures. The most stable stoichiometry of heavy alkali-metal GIC's is shownto be MC.... at ambient pressure, but MC... at higher hydrostatic pressure.Comparison is made of the theoretical results with the experimental ones atfinite temperatures.
- 社団法人日本物理学会の論文
- 1984-04-15
著者
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Kuramoto Yoshio
Department Of Applied Physics Tohoku University
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Miyazaki Hiroshi
Department Of Cardiology Kyoto First Red Cross Hospital
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Horie Chuji
Department Of Applied Physics Faculty Of Engineering Tohoku University
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Kuramoto Yoshio
Department Of Applied Physics Faculty Of Engineering Tohoku University
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Miyazaki Hiroshi
Department Applied Physics Tohoku University
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