Dielectric Studies of Hydrogen Bonded Complexes Tri-n-Butyl Phosphate (TBP) with Long-Chain Aliphatic Alcohols

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概要

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• The mechanism of dipolar complexation involving TBP and three long chain aliphatic alcoholsnamely 1-hexanol, l-heptanol, l-octanol in a non-polor medium (benzene) was investigated fromdielectric measurements at frequency 455 kHz and at tenuperature 303.16 K using modified Palit'smethod. The dipole moment of the complex (p5.), interaction dipole mornent (,47?), dipolemoment of the H-bonded bridge (p') and induced polarization (,47') for the thermodynamicallymost favoured geometry of l:l complexes of these systems were computed. The results showsthat cornplexation is due to partial proton transfer in all the cases studied and the tendency ofcornplex formation is maximum in 1-heptanol systeun.

• 社団法人日本物理学会の論文
• 1996-10-15

著者

• Swain B

  Post Graduate Department Of Physics Ravenshaw College

• DASH S.K.

  Department of Physics,Kshetrabasi Dayananda Anglo Vedic College

• SWAIN B.B.

  Post Graduate,Department of Physics,Ravenshaw College

• Swain B.b.

  Post Graduate Department Of Physics Ravenshaw College

• Dash S

  Department Of Physics Kshetrabasi Dayananda Anglo Vedic College

• Dash S.k.

  Department Of Physics K.b.d.a.v. College

関連論文

• Dielectric Studies of Hydrogen Bonded Complexes Tri-n-Butyl Phosphate (TBP) with Long-Chain Aliphatic Alcohols
• Molecular Interaction in a Polar-Polar System-Methyl Isobutyl Ketone (MIBK) and Primary Aliphatic Alcohols : Using Dielectric Measurements
• Dipolar Association in Binary System: MIBK in Carboxylic Acids

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