Small-Angle X-Ray Scattering from the Surfaces of Polymer Crystals
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概要
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Surface structure of polyethylene crystals is examined by small-angle X-ray scattering (SAXS). Folded chain crystals crystallized isothermally and extended chaincrystals annealed isothermally showed SAXS obeying the Porod's law in a range ofscattering vector from 10 " to 10 "" A '; the surfaces of these crystals are smoothabove a scale of length of 20 A. This result suggests that the thickening process ofpolymer crystals is controlled by nucleation and growth. Fractal surfaces reportedpreviously are related with the fluctuation of driving force for the thickening; the fluctuation has power-law correlation in space or time.[SAXS, polymer, surface, fractal, polyethylene, Porod's law, Langevin equa- ll lion, fractional Brownian surface, poxver-lawl
- 社団法人日本物理学会の論文
- 1990-10-15
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