Electron Paramagnetic Resonance of Tl^<2+>:A Probe for the Dynamic Sulfate Disorder in α-Alums
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概要
- 論文の詳細を見る
Electron paramagnetic resonance of KAI(SO.).- l2H.O and NH.Al(SO.).- 12H.Odoped with Tl" was investigated in the interval of temperature 65 K-160 K. Thechanges in the EPR spectra of the Tl" ion in both doped crystals are discussed basedon the influence of a reorientational model for sulfate groups. A model to explain con-flicting data reported in the literature and concerned with the presence of a phase Iransition in non-polarizable cz-alums is suggested. Also, the changes of the EPRparameters near the phase transition in polarizable cx- and /7-alums are discussed here.
- 社団法人日本物理学会の論文
- 1988-08-15
著者
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Chaves A.S.
Departamento de Fisica,instituto de Ciencias Exatas,Universidade Federal de Minas Gerais
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Ribeiro G.M.
Departamento de Fisica,instituto de Ciencias Exatas,Universidade Federal de Minas Gerais
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Chaves A.S.
Departamento de Fisica,Universidade Federal de Minas Gerais
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Morais P.C.
Laboratorio de Estado Solido Departamento de Fisica Universidade de Brasilia
関連論文
- Phase Transition Structural Changes of Rb_2Cd_2(SO_4)_3 Investigated by Electron Paramagnetic Resonance of the Tl^Ion
- Thermal Diffusion Dispersion in Disordered Systems
- Electron Paramagnetic Resonance of Tl^:A Probe for the Dynamic Sulfate Disorder in α-Alums