Temperature Dependence of Fine Structure of Mn^<2+> Ions in Alkali Chlorides

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概要

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• The paramagnetic resonance spectra of Mn^<2+> in three alkali chlorides, i.e., LiCl, NaCl and KCl were measured over the temperature range from room to liquid nitrogen temperature. The fine structure constants D and E of a Mn^<2+>-vacancy center varied linearly with temperature. In LiCl, these constants were almost insensitive to temperature. In NaCl and KCl, the constants were appreciably dependent on temperature, and the fractional changes of those were larger in KCl than in NaCl by a factor of about three. The behaviours under temperature were qualitatively interpreted from the view point of the ionic arrangements around Mn^<2+>.

• 社団法人日本物理学会の論文
• 1970-10-05

著者

• Iri Takeo

  The University of Electro-Communications

• KOHNO Katsuyasu

  The University of Electro-communications

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