In situ Spectroscopy of Solid-State Chemical Reaction in PbBr_2-Deposited CsBr Crystals
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概要
- 論文の詳細を見る
It is possible to measure the fundamental optical absorption spectra of CsPbBr_3 and Cs_4PbBr_6, whose stability is predicted by the study of phase diagram in the binary system CsBr-PbBr_2, by means of in situ optical absorption and reflection spectroscopy of thermally induced solid-state chemical reaction in PbBr_2-deposited CsBr crystals. On heavy annealing of the crystals, the Pb^<2+> ions are uniformly dispersed in the crystal matrix. The present experiment provides a novel method for measuring intrinsic optical absorption of ternary metal halides and also for in situ monitoring of doping metal halide crystal with impurities (metal ions or halogen ions).
- 社団法人日本物理学会の論文
- 2003-09-15
著者
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Saito T
Plasma Research Center University Of Tsukuba
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KONDO Shin-ichi
Research Center of Production Technology, Zeon Corp.
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Saito T
Univ. Tsukuba Ibaraki
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Kondo Shin-ichi
Research Center For Development Of Far-infrared Region Fukui University
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Kondo S
Department Of Materials Science And Engineering Nagasaki University
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Asada Hiroshi
Department of Applied Physics, Faculty of Engineering, Fukui University
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Asada Hiroshi
Department Of Applied Physics Faculty Of Engineering Fukui University
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Saito Tadaaki
Research Center For Development Of Far-infrared Region Fukui University
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MATSUNAGA Toshihiro
Department of Applied Physics, Faculty of Engineering, Fukui University
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Matsunaga Toshihiro
Department Of Applied Physics Faculty Of Engineering Fukui University
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Asada Hiroshi
Department Of Applied Physics Faculity Of Engineering Fukui University
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