On the Phase Transition in Barium-Lead Titanate.
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The temperature change in lattice parameters of solid solutions of barium titanate containing 10, 12, 20 and 25 mole per cent of lead titanate have been studied mainly by the X-ray method for the range from -130℃ to 300℃. It was found that the lattice parameter・temperature curves for the solid solutions of 12 and 20 per cent lead titanate have characteristic features as follows: (1) a-parameter・temperature curves show a considerable linearity from lower temperatures up to the Curie point. (2) A large amount of discontinuity of a- and c-parameters takes place at the Curie point. (3) The superposition of cubic lines upon tetragonal lines is observed in a temperature range near the Curie point. The lattice volume calculated from tetragonal phase shows an abnormal contraction. These results are not explained by the Devonshire's theory in its original form, but they can be explained fairly well by using higher order approximation.
- 社団法人日本物理学会の論文
- 1951-10-25
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関連論文
- On the Phase Transition in Barium-Lead Titanate (1).
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- Crystal Structure of Lead Titanato and of Lead-Barium Titanate
- Phase Transitions in Solid Solutions of PbZrO_3 and PbTiO_3 (II) X-ray Study
- Crystal Structure of Pb(Zr-Ti)O_3
- X-ray Studies on the Structures of Solid Solutions NaCl-CaCl_2 : II. Structures of {111} and {310} Plate-Zones
- X-ray Studies on the Structures of Solid Solutions NaCl-CaCl_2 : III. Influence of Heat Treatments on the Diffuse Reflexions of X-rays due to {111} and {310} Plate-Zones
- On the Phase Transition in Barium-Lead Titanate.