C^<13>-H Coupling in Hydrocarbon Molecules

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概要

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• The electron coupled nuclear spin-spin interaction between a C^<13> and a proton in a chemical bond in hydrocarbon molecules is investigated theoretically. The lower limit of an electronic correlation effect on the coupling constant is estimated semi-empirically. The result shows that the coupling constant is inversely proportional to the valence number of the C^<13> atom, and is almost unaffected by a substitution at the end of the molecule, if the symmetry of the molecule is not altered by the substitution.

• 一般社団法人日本物理学会の論文
• 1967-11-05

著者

• Hiroike Eiko

  Chemical Research Institute of Non-Aqueous Solutions, Tohoku University

関連論文

• C^-H Coupling in Hydrocarbon Molecules

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