Zeeman Effect of Nuclear Quadrupole Resonance Spectrum in 1, 3, 5-Trichlorobenzene
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概要
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A study of the Cl^<35> resonance spectrum was carried out at the room temperature on a single crystal of 1, 3, 5-trichlorobenzene. Spatial orientation of the C-Cl bonds was determined to the accuracy of 1°. An orthorhombic structure was concluded, with the unit cell containing at least four equivalent molecules oriented with the symmetry of D_<zh>. The angles between the C-Cl bonds in each molecule were close to the hexagonal angle, but one of the C-Cl bonds was deformed by ca. 1.6° from the plane of the other two. The asymmetry parameters were observed to be 0.09_3, 0.11_1, and 0.12_g for three absorption lines, 35.020Mc, 35.296Mc, and 35.545Mc, respectively. The results were discussed from the viewpoint of intermolecular interaction.
- 社団法人日本物理学会の論文
- 1960-02-05
著者
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Toyama Masaharu
Department Of Chemistry Faculty Of Science University Of Tokyo
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MORINO Yonezo
Department of Chemistry, Faculty of Science, The University of Tokyo
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Morino Yonezo
Department Of Chemistry Faculty Of Science University Of Tokyo
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Morino Yonezo
Department Of Chemistry Faculty Of Science The University Of Tokyo
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Toyama Masaharu
Department of Chemistry Faculty of Science The University of Tokyo
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MORINO Yonezo
Department of Chemistry, Faculty of Science, University of Tokyo
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