Theory of Dilute Polymer Solutions (II) : Osmotic Pressure
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概要
- 論文の詳細を見る
A statistical-mechanical theory of dilute polymer solutions is developed following the solution theory of McMillan and Mayer, and the osmotic second virial coefficient A_2 is calculated taking account of the intra- and intermolecular interactions. The final expression for A_2 is expressed in terms of the molecular constants such as the molecular weight, segment size and bond length. The molecular weight dependence of A_2 is improved at least in the vicinity of the Flory point in comparison with the theories of Flory-Krigbaum and Isihara-Koyama.
- 社団法人日本物理学会の論文
- 1958-01-05
著者
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YAMAKAWA Hiromi
Department of Textile Chemistry, Kyoto University
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Yamakawa Hiromi
Department Of Polymer Chemistry Kyoto University
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