Charge Transfer in Donor-Acceptor Crystalline Complexes

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概要

• 論文の詳細を見る

• The pressure-induced neutral-tonic transition of TTF-DIVIDCNQI complex is analyzed by usinga simple dimer model with electron-intramolecular vibration coupling. The coupling is shownto be responsible for a sharp neutral-ionic phase transition and characteristic hysteresis in thedegree of ionicity dependence upon pressure in this complex. Ground state charge distributionis calculated as a function of small-polaron binding energies and transfer integral between donorand acceptor sites.

• 社団法人日本物理学会の論文
• 1996-03-15

著者

• Matsuzaki Susumu

  Department Of Chemistry Faculty Of Sciences Kumamoto University

• Matsuzaki Susumu

  Department Of Chemistry Faculty Of Science Kumamoto University

• BASAKI Shinya

  Department of Chemistry,Faculty of Sciences,Kumamoto University

• Vyacheslav M.

  Centro de Fisica,Instituto Venezolano de Investigaciones Cientificas

• Basaki Shinya

  Department Of Chemistry Faculty Of Sciences Kumamoto University

• Vyacheslav M.

  Centro De Fisica Instituto Venezolano De Investigaciones Cientificas

• Yartsev Vyacheslav

  Centro de Fisica,Instituto Venezolano de Investigaciones Cientificas

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• IR spectra of solid state reaction products of TTF and iodine.
• Resonance raman spectra of tetracyanoethylene anion dimers.
• Polarization dispersion in the resonance raman spectra of EDA complexes with TCNE and TCNB.

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