XPS and UPS Studies of Valence Fluctuation and Surface States of Yb_4As_3,Yb_4Sb_3 and Yb_4Bi_3

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概要

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• X-ray and vacuum ultraviolet photoemission spectra were measured for valencefluctuating Yb.X. (X: As, Sb and Bi) by use of Mg K. and synchrotron radiationsource. From the line shape analysis of the Yb 4f spectra, the mean valence isevaluated as 2.32, 2.34 and 2.10 for Yb.As., Yb.Sb. and Yb.Bi.. The surface Yb 4flevel shift is estimated as 0.65, 0.63 and 0.59 eV, respectively. The plasmon satellite isconfirmed in the Yb 4f and Yb 4d core XPS spectra of Yb.Bi. in contrast to those inYb.As, and YbAs. As for the anionic states, the Bi 5d core UPS spectrum showed aremarkable asymmetry in contrast to the rather symmetric Bi 4f core XPS spectrum.This result suggests a contribution of the surface Bi 5d state at larger binding energiesof about 0.5 eV.

• 社団法人日本物理学会の論文
• 1989-12-15

著者

• OCHIAI Akira

  Department of Physics, Graduate School of Science, Tohoku University

• SUZUKI Takashi

  Department of Biochemistry, University of Shizuoka, School of Pharmaceutical Sciences, Core Research

• TAGUCHI Munetaka

  RIKEN/SPring-8

• Suga Shigemasa

  Synchrotron Radiation Laboratory Institute For Solid State Physics The University Of Tokyo

• OH Se-Jung

  Department of Physics,Seoul National University

• Namatame Hirofumi

  Department Of Physics Faculty Of Science University Of Tokyo

• Ishii Takehiko

  Institute For Solid State Physics University Of Tokyo

• Arai Kuniaki

  Institute For Solid State Physics University Of Tokyo

• Takata M

  Department Of Physics Division Of Material Science Nagoya University

• KASUYA Tadao

  Department of Physics,Faculty of Science,Tohoku University

• Namatame H.

  Hsrc Hiroshima Univ.

• Kato Hiroo

  Photon Factory, National Laboratory for High Energy Physics (KEK)

• Miyahara Tsuneaki

  Photon Factory, National Laboratory for High Energy Physics (KEK)

• Ishii T

  Institute For Solid State Physics University Of Tokyo

• Kasuya A

  Tohoku Univ. Sendai Jpn

• Kimura A

  Univ. Tokyo Chiba

• Ochiai Akira

  The Oarai Branch Institute For Materials Research Tohoku University

• Ochiai Akira

  Department Of Material Science And Technology Faculty Of Engineering Niigata University

• FUJIMORI Atsushi

  National Institute for Research in Inorganic Materials

• Taniguchi Masaki

  Synchrotron Radiation Laboratory Institute For Solid State Physics The University Of Tokyo

• Oh S‐j

  Seoul Nationlal Univ. Seoul Kor

• Oh Se-jung

  Department Of Physics Seoul National University

• Ogawa S

  Osaka City Univ. Osaka

• Kasuya Tadao

  Department Of Physics Faculty Of Science Tohoku University

• Kato H

  Faculty Of Science Kwansei-gakuin University

• Iwasaki T

  National Inst. Industrial Health Kawasaki Jpn

• Iwasaki Takeshi

  National Institute Of Industrial Health 21-1 Nagao 6-chome Tama-ku Kawasaki 214 Japan

• ISHII Takehiko

  Synchrotron Radiation Laboratory, Institute for Solid State Physics, University of Tokyo

• OGAWA Susumu

  Synchrotron Radiation Laboratory,Institute for Solid State Physics, University of Tokyo

• NAMATAME Hirofumi

  Synchrotron Radiation Laboratory,Institute for Solid State Physics, University of Tokyo

• KAKIZAKI Akito

  Synchrotron Radiation Laboratory,Institute for Solid State Physics, University of Tokyo

• Miyahara Tsuneaki

  Photon Factory Kek

• Ogawa Susumu

  Second Department Of Internal Medicine Tohoku University School Of Medicine

• Ogawa Susumu

  Synchrotron Radiation Laboratory Institute For Solid State Physics The University Of Tokyo

• Kakizaki Akito

  Department Of Physical Sciences Hiroshima University

• Kimura Akio

  Institute Of Materials Structure Science High Energy Accelerator Research Organization

• Kakizaki Akito

  Synchrotron Radiation Laboratory Institute For Solid State Physics The University Of Tokyo

• Kimura A

  Institute For Solid State Physics University Of Tokyo

• Ogawa Shinji

  Institute For Solid State Physics University Of Tokyo

• Kato Hiroo

  Photon Factory High Energy Accelerator Research Organization

• Suzuki Takashi

  Department Of Biochemistry University Of Shizuoka School Of Pharmaceutical Sciences:core Research Fo

• Suzuki Takashi

  Department Of Anesthesia Showa University Northern Yokohama Hospital

• Suzuki Takashi

  Department Of Anatomic Pathology Tohoku University School Of Medicine

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