Reactions of Highly Excited Atoms with Molecules A+BC→A^+B+C^-
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概要
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Reactions of highly excited atoms (A) with molecules (BC) A+BC⇾A^++B+C^-, (1) are studied. It is theoretically shown that the cross section for (1) can be approximately expressed in terms of that for dissociative attachment of electrons to molecules BC, namely, e+BC⇾B+C^-. The rate constants and the angular distributions of the products for some reactions including K_r+CCl_4⇾K_r^-++CCl_3+Cl^-, (2) are predicted. The rate constant for reaction (2) is found to be of the order of the magnitude 10^<-7>cm^3/sec. Together with the results of the previous papers (M. Matsu zawa: J. chem. Phys. 55(1971) 2685; J. Phys. Soc. Japan 32 (1972) 1088) it is pointed out that the measurements of reactions of highly excited atoms with molecules give useful information on the inelastic scattering of a slow electron by the molecules.
- 社団法人日本物理学会の論文
- 1972-10-05
著者
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Matsuzawa Michio
Department Of Applied Physics And Chemistry
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Matsuzawa Michio
Department Of Applied Physics The University Of Electron-communications
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