Nuclear Quadrupole Resonance in Hexachloro-Ethane

スポンサーリンク

概要

• 論文の詳細を見る

• The temperature dependence of nuclear quadrupole resonance frequency has been studied in hexachloroethane. The intensities of four lines are in the ratio 2:2:1:1 which is equal to the ratio of distribution of chlorine atoms amongst various positions in the unit cell. The analysis of the data indicates that lattice vibration, rotation of the whole molecule and internal rotation of C-Cl_3 groups are active in modulating the electric field gradient at the chlorine nuclei. These modes possess Einstein temperatures of 26 K, 72 K, and 114 K respectively. Eech of the C-Cl bonds is found to have fractional S-character and ionic contribution of 12% and 16% respectively.

• 1972-01-05

著者

• Singh Kartar

  Defence Science Laboratory

関連論文

• Nuclear Quadrupole Resonance in Hexachloro-Ethane
• Nuclear Quadrupole Resonance in Tin Compounds

スポンサーリンク