Ionic Conductivity of Lead Chloride Crystals
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概要
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The ionic conductivity of single crystals of pure and KCl-and NaCl-doped PbCl_2 has been measured between 90 and 400℃. The thermal disorder appears to be of unassociated Schottky defects. The expressions for the "mobility" μ and the "concentration" x_n^0 of anion vacancies have been determined from a comparison between the observed isothermals and those predicted from the simple theory of Koch and Wagner in which association effects are omitted. The experimental expressions are μ=(2.6×10^<-1>/T)exp(-0.20±0.03/kT)cm^2volt^<-1>sec^<-1> and x_n^0=2.7×10^2exp(-0.51±0.05/kT) in mole fraction, where kT is expressed in electron-volt. These are the first results, expressed as a function of temperature, for anion vacancies in PbCl_2 crystals.
- 社団法人日本物理学会の論文
- 1969-06-05
著者
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NAKAMURA Yoshio
Department of Chemistry, Faculty of Sciece, Konan University
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Hoshino Hideoki
Department Of Chemistry Faculty Of Science Hokkaido University:department Of Chemistry Faculty Of Ed
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Hoshino Hideoki
Department Of Chemistry Faculty Of Science Hokkaido University
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YAMAZAKI Masaaki
Department of Chemistry, Faculty of Science, Hokkaido University
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SHIMOJI Mituso
Department of Chemistry, Faculty of Science, Hokkaido University
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Shimoji Mituso
Department Of Chemistry Faculty Of Science Hokkaido University
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Yamazaki Masaaki
Department Of Chemistry Faculty Of Science Hokkaido University
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Nakamura Yoshio
Department Od Metallurgical Engineering Tokyo Institute Of Technology
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