Optical and Thermal Conversion of V_k Centers in X-Irradiated Hydroxylammonium Chloride

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概要

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• The Cl^-_2 centers trapped in X-irradiated single crystals of hydroxylammonium chloride have been studied by electron spin resonance technique in the temperature range from 77°K to 150°K. Two crystallographically inequivallent Cl^-_2 centers designated as V_k(I) and V_k(II) are produced in the crystal. The former is composed of a chlorine ion pair situated on the bc plane and the latter is formed from a pair on the plane nearly perpendicular to the bc plane. Thermal conversion from V_k(I) into V_k(II) takes place thermally above 105°K and V_k(II) is converted into V_k(I) by irradiation with the V_k light at 77°K.

• 社団法人日本物理学会の論文
• 1969-03-05

著者

• Kurita Yukio

  Basic Research Laboratories Toyo Rayon Co. Ltd.

• Ohigashi Hiroji

  Basic Research Laboratories Toray Industries Inc.

• Ohigashi Hiroji

  Basic Research Laboratories Toyo Rayon Co. Ltd.

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• Optical and Thermal Conversion of V_k Centers in X-Irradiated Hydroxylammonium Chloride
• Electron Spin Resonance Spectra of X-Irradiated Single Crystals of Syn-and Anti-p-Chlorobenzaldoxime : Trapping of Syn-and Antu-Iminoxy Radicals, and of Their Radical Pairs
• Electron spin resonance study of X-irradiated single crystals of silver(I) nitrate-butanedinitrile (1/1).
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