_c-Axis Compressibility and Thermal Expansion of Gold Trichloride-Graphite Intercalation Compounds (AuCl_3-GICs)
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概要
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We investigated c-axis compressibility and thermal expansion of the first and the second stage AuCl_3-GICs in order to clarify the c-axis lattice dynamical properties related to the specific structure of AuCl_3 intercalates. The results are explained in terms of not only the (00l) longitudinal acoustic phonons but also the libron mode, in which the libronic motion of planar Au_2Cl_6 molecules plays an important role, in the case of the first stage compound. The acoustic phonon analyzed based on one-dimensional Debye model gives the Debye temperature Θ_<1dD>=444K with the Gruneisen constants Γ=2.49, while the contribution of the libron has the characteristic energy of Θ_E=33K and the Gruneisen constant Γ=0. 46. c-axis thermal expansion of the second stage compound is explained in terms of the acoustic and the high energy optic phonon modes which have Θ_<1dD>=306K and Θ_E=320K, respectively, since the c-axis zone folding makes the energy of the optic phonon mode lowered.
- 社団法人日本物理学会の論文
- 1995-12-15
著者
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ENOKI Toshiaki
Department of Chemistry,Graduate School of Science and Engineering,Tokyo Institute of Technology
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SHIROTANI Ichimin
Department of Electric and Electronic Engineering, Muroran Institute of Technology
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ISHII Tomohiko
Department of Chemistry, Tokyo Metropolitan University
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Shirotani Ichimin
Department Of Electrical And Electronic Engineering Muroran Institute Of Technology
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Shirotani Ichimin
Department Of Applied Science For Energy Muroran Institute Of Technology
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Ishii Tomohiko
Department Of Advanced Materials Science Faculty Of Engineering Kagawa University
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Ishii Tomohiko
Department Of Chemistry Tokyo Institute Of Technology
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SUGIHARA Ko
College of Pharmacy,Nihon University
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SHIBAYAMA Yoshiyuki
Department of Chemistry, Tokyo Institute of Technology
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Bandow Syunji
Instrument Center, Institute for Molecular Science
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Sugihara Ko
College Of Pharmacy Nihon University
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Bandow S
Inst. Molecular Sci. Okazaki Jpn
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Enoki Toshiaki
Department Of Chemistory Tokyo Inst.of Technology
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Bandow Syunji
Instrument Center Institute For Molecular Science
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Shibayama Yoshiyuki
Department Of Chemistry Tokyo Institute Of Technology
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