Flow Properties of Multilamellar Droplets in AOT/Brine/Glycerol Mixtures(Condensed Matter : Structure, Mechanical and Thermal Properties)
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概要
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The properties of lamellar solutions formed in a quaternary mixture made of brine, sodium bis(2-ethylhexyl) sulfosuccinate (AOT), and glycerol have been studied under shear flow. As in AOT, brine pseudo-ternary system, the lamellar solutions exhibit a structural transition above a threshold shear rate, and form quasi-monodispersed multilamellar droplets. In this regime, the solutions are shear thinning. Both the viscosity and the droplet size scale with the shear rate with exponents respectively equal to -0.7 and -0.4. This last value is smaller than the one, 0.5, reported in the ternary systems. Tentative explanations of our experimental results are given.
- 社団法人日本物理学会の論文
- 2004-09-15
著者
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Ushiki Hideharu
Departament De Tecnologia De Tensioactius
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Ishii A
Laboratory Of Molecular Dynamics And Complex Chemical Physics Department Of Environmental And Natura
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ISHII Akiko
Laboratory of Molecular Dynamics and Complex Chemical Physics, Department of Environmental and Natur
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PONS Ramon
Laboratory of Molecular Dynamics and Complex Chemical Physics, Department of Environmental and Natur
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ROUGH Jacques
Centre de Physique Moleculaire Optique et Hertzienne
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LETAMENDIA Louis
Centre de Physique Moleculaire Optique et Hertzienne
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Pons Ramon
Laboratory Of Molecular Dynamics And Complex Chemical Physics Department Of Environmental And Natura