Electrostatic Interaction of d^n Systems in Tetragonal Fields

スポンサーリンク

概要

• 論文の詳細を見る

• Energy levels of nd transition metal ions in a ligand field of the tetragonal symmetry are studied in the strong field approximation. In this field, d level is split into four sub-levels differing in energy, of symmetry b_1, a_1, e and b_2 respecively. Starting from the configurations containing these orbitals, Coulomb interaction between electrons is introduced, which gives rise to energy levels, each characterized by ST. Matrix elements of Coulomb interaction are expressed in terms of Racah's parameters A, B and C with the ligand field parameters X, Y and Z which give the intervals between orbital energies. These matrix elements are shown for d^2, d^3, d^4 and d^5.

• 社団法人日本物理学会の論文
• 1966-04-05

著者

• OTSUKA Jinya

  Department of Applied Biological Sience, Faculty of Science and Technology,Science University of Tok

• Otsuka Jinya

  Department Of Physics Faculty Of Science University Of Tokyo

• Otsuka Jinya

  Department Of Applied Biological Science Science University Of Tokyo

• Otsuka J.

  Department of Physics, Faculty of Science, University of Tokyo

関連論文

• Heitler-London Calculation on the Bonding of Oxygen to Hemoglobin. : III. Singlet States in the Case of O-O Axis Inclined to Heme Plane
• Heitler-London Calculation on the Bonding of Oxygen to Hemoglobin. : II. Explanation of the Diamagnetism of Oxyhemoglobin for the Parallel Arrangement of O_2 to the Heme
• Heitler-London Calculation on the Bonding of Oxygen to Hemoglobin. : I. Singlet States in the Case of O-O Axis Parallel to Heme Plane
• Electrostatic Interaction of d^n Systems in Tetragonal Fields
• Asymptotic Property of Probability Distribution in the Relaxation from an Unstable Point : Path Integral Approach
• Fine Structures of Iron Ions in Hemoproteins

スポンサーリンク