Crystal Structure of Cupric Benzoate Trihydrate Cu(C_6H_5COO)_23H_2O

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概要

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• Cupric benzoate trihydrate crystallizes in the monoclinic system, space group I2/c, with four formula units in a unit cell of dimensions, a=6.98, b=34.12, c=6.30Å; β≒90°. There are two kinds of benzoate groups. The carboxyl oxygen atoms of benzoate group I are in direct contacts with copper atoms, while those of group II are coordinated to copper atoms through water molecules. Each copper atom is situated at the center of a deformed octahedron consisted of four water molecules and two oxygen atoms from benzoate group I. The octahedra are linked, by sharing two water molecules, into a column parallel to the c-axis. Within this column, copper atoms lie on a line at an interval of 3.15Å, which suggests the presence of magnetic anisotropy.

• 社団法人日本物理学会の論文
• 1963-01-05

著者

• Koizumi Hideo

  Department Of Physics Osaka University:electrical Communication Laboratory Nippon Telegraph And Tele

• Osaki Kenji

  Department Of Physics Faculty Of Science Osaka University:(present Address) Faculty Of Pharmaceutica

• Osaki Kenji

  Department Of Physics Osaka University

• WATANABE Tokunosuke

  Department of Physics, Osaka University

• Watanabe Tokunosuke

  Department Of Physics Faculty Of Science Osaka University:(present Address) Department Of Chemistry

• Koizumi H.

  Department Of Mechanical Engineering & Intelligent Systems The University Of Electro-communicati

• Osaki Kenji

  Department of Applied Science,Faculty of Engineering,Kyushu University

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