On the Electronic Structure of the U_2-center in KCl Crystals, I.

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概要

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• The electronic structure of the U_2 center is studied by using the so called "point ion lattice model". The wave function which is obtained for the ground state of the U_2 center by considering the effects of various kinds of interactions, is applied to analyze the observed data of E.S.R. The is wave function of the free hydrogen orthogonalized to the core orbitals of the surrounding ions gives us the interpretation of E.S.R. in the order of magnitude, however, there still remain some discrepancies between the calculated and the observed values. The physical origins of these discrepancies are considered. The large zero point vibration of the U_2 center suggests to us that the width of the absorption curve of E.S.R. is broadened about 20% by the vibration. Discussions on the effect of polarization, of crystalline field and on the optical absorption are made briefly by assuming the point ion and dipole approximation.

• 社団法人日本物理学会の論文
• 1959-08-05

著者

• Uemura Yasutada

  Department Of Dynamics Faculty Of Engineering Tokyo University

• Mimura Hiroshi

  Department Of Applied Physics University Of Tokyo

• Mimura Hiroshi

  Department Of Applied Physics Faculty Of Engineering University Of Tokyo

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