Paramagnetic Resonance Absorption in Chromous Sulphate Pentahydrate
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概要
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The paramagnetic resonance spectra of Chromous sulphate pentahydrate have been analyzed at room temperature for the wavelengths between 0.54cm and 1.1cm. The results show that this crystal has a structure similar that of copper sulphate pentahydrate. The observed data have been analyzed by the so-called spin Hamiltonian and the positions and intensities of the absorption lines are adequately explained by a crystalline electric field of rhombic symmetry. The parameters determined have been found to be quite consistent with the values of the spin-orbit coupling constant and spin-spin interaction constant obtained from spectroscopic data. The line width varies from 1K oer. to 3K oer. with the direction of the magnetic field and high frequency field and seems to be broader than that expected from magnetic dipolar interaction alone.
- 社団法人日本物理学会の論文
- 1957-11-05