Properties of d-Electrons in Complex Salts. Part III : Detailed Studies of the Line Spectra

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概要

• 論文の詳細を見る

• Experimental and theoretical studies previously done on the line spectra of transition metal ions in crysta's are summarized. Theoretical analyses free from any ambiguous quantities are attempted. The subjects discussed here are therefore mainly restricted to the qualitative nature of the Zeeman effects and optical anisotropies of the line spectra. Electric dipole transitions caused by small odd crystal fields and odd vibrations are discussed in detail, with special reference to vanadium and chromium corundum and chromium alums. In connection with the Zeeman effect of the absorption lines of chromium alums, vibronic problems of the excited doublet states of d^3 systems are also treated. Some magnetic dipole transitions in MnSiF_6・6H_2O crystals are quantitatively discussed. It is pointed out that their intensities are of comparable order of magnitude to those of the electric dipole transitions in the same crystal.

• 理論物理学刊行会の論文

著者

• Sugano Satoru

  Department Of Physics Faculty Of Science University Of Tokyo

関連論文

• Absorption Spectra of Cr^ in Al_2O_3 : Part A. Theoretical Studies of the Absorption Bands and Lines
• Absorption Spectra of Cr^ in Al_2O_3 : Part B. Experimental Studies of the Zeeman Effect and Other Properties of the Line Spectra
• Magnetic Properties of the Pd and Pt Group Transition Metal Complexes
• An Application of the Thomas-Fermi Method to Complex Ions
• Anomalous g-shifts of Excited States of Cr^ in Ruby
• Properties of d-Electrons in Complex Salts. Part III : Detailed Studies of the Line Spectra
• Luminescence Processes in the KCl:Tl Phosphor in a Multidimensional Configuration Space

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