3B02 高分子-液晶混合系の臨界ネマチック核(生体関連・リオトロピック液晶)

概要

論文の詳細を見る
We theoretically study the nucleation of nematic droplets during phase ordering in mixtures of a flexible polymer and a low molecular weight liquid crystal. By appealing to classical nucleation theory (CNT), we calculate the energy barrier to nucleation and the size of a critical nucleus. We study the influence of a metastable intermediate phase on the nucleation of the nematic. Below a triple point in the phase diagram, there are two distinct mechanisms for the formation of a nematic nucleus : (1) direct nucleation from the isotopic phase and (2) nucleation via a precursor metastable isotropic phase. We calculate the crossover concentration as a function of temperature, delineating the regions of the phase diagram in which each mechanism prevails. In the latter case, the presence of a hidden metastable isotropic-isotropic binodal may either promote or delay the nucleation of a nematic phase.
日本液晶学会の論文
2002-10-09