The Polarity of the Diatomic Molecule

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概要

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• The relation between the ionicity of the bond and the electronegativity difference is discussed by the use of the semi-localized orbital method. It is found that the ionicity of the bond depends not only on the electronegativity difference but also on the overlap integral between the atomic valence orbitals. According to the magnitude of the overlap integral the diatomic molecules are divided into the two groups which show the different features with respect to the dependence of the ionicity of the bond on the electronegativity difference. The S-shaped curve given by Townes and Dailey from the analysis of the results of the measurements of eQq seems to be the composite of the above two characteristic groups.

• 理論物理学刊行会の論文
• 1961-02-25

著者

• O-ohata Kiyosi

  Physics Department Tokyo Institute Of Technology

• O-ohata Kiyosi

  Physics Department Tokyo Institute Of Technology Oh-okayama

• O-OHATA Kiyosi

  Physics Department, Tokyo Institute of Technology Oh-okayama

関連論文

• The Binding Energy of the σ Bond, II. Application to the Diamond Crystal
• The Polarity of the Diatomic Molecule
• The Binding Energy of the σ Bond, I. General Theory
• The Binding Energy of the σ Bond. IV. : Discussion on the Higher Order Terms

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