ヘテロレプチック型亜鉛アート錯体の設計と機能
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概要
- 論文の詳細を見る
Organometallic reagents having Lewis acidity (such as dialkylzincs) often form complexes with anion species (such as alkyllithiums) to generate ate complexes (such as lithium trialkylzincates). Since all of ligands coordinated to Zn are usually the same (homoleptic), these reactivities, i.e., the magnitude of the transference aptitude of ligands, are essentially equivalent. However, the reactivities of the ligands should be nonequivalent, if different ligands do coordinate to Zn (heteroleptic). Such heteroleptic zincates and their practical applications for organic transformations has been investigated and discussed theoretically based on computational methods.
- 社団法人 有機合成化学協会の論文
- 2008-01-01