Redox Equilibrium of U^<4+>/U^<3+> in Molten NaCl-2CsCl by UV-Vis Spectrophotometry and Cyclic Voltammetry
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概要
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In order to investigate the redox equilibrium of uranium ions in molten NaCl–2CsCl, UV–Vis absorption spectrophotometry measurements were performed for U4+ and U3+ in molten NaCl–2CsCl at 923 K under simultaneous electrolytic control of their ratio. Prominent absorption bands at 480 and 570 nm were assigned to U3+, and their molar absorptivities were determined to be 1,260±42 and 963±32 mol−1·l·cm−1 respectively. From the dependence of the rest potential of the melt on the spectrophotometrically determined ratio of [U4+]/[U3+], the standard redox potential of the couple U4+/U3+ at 923 K was determined to be −1.481±0.004 V vs. Cl2/Cl−. Cyclic voltammetry measurements were carried out for the couple U4+/U3+, and the results agreed well with this standard redox potential value. By the results of cyclic voltammetry, a temperature dependence of the standard redox potential was found to be −2.094+6.639×10−4T (T=823–923 K).
- 社団法人 日本原子力学会の論文
- 2005-12-25
著者
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Shirai Osamu
Div. Of Applied Life Sciences Graduate School Of Agriculture Kyoto Univ. Sakyo Kyoto 606-8502 Jpn
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Shirai O
Institute For Chemical Research Kyoto University
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YAMANA Hajimu
Research Reactor Institute, Kyoto University
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SATO Nobuaki
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
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Shirai Osamu
Division Of Nuclear Engineering Science Research Reactor Institute Kyoto University
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Shirai Osamu
Research Reactor Institute Kyoto University
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Shirai Osamu
Department Of Nuclear Energy System Japan Atomic Energy Research Institute
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Fujii Toshiyuki
Research Reactor Institute Kyoto University
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UEHARA Akihiro
Research Reactor Institute, Kyoto University
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Nagai Takayuki
Japan Atomic Energy Agency
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NAGAI Takayuki
Nuclear Fuel Cycle Engineering Laboratories, Japan Atomic Energy Agency
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Yamana H
Research Reactor Institute Kyoto University
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Yamana Hajimu
Research Reactor Institute Kyoto University
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Uehara Akihiro
Research Reactor Institute Kyoto University
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Sato Nobuaki
Institute Of Multidisciplinary Research For Advanced Materials Tohoku University
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Sato Nobuaki
Institute For Advanced Materials Processing Tohoku University
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Shirai O
Research Reactor Institute Kyoto University
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Nagai Takayuki
Oriental Medicine Res. Center Of The Kitasato Inst. Tokyo Jpn
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Yamana Hajimu
Res. Reactor Inst. Kyoto Univ.
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Shirai Osamu
Division Of Applied Life Science Graduate School Of Agriculture Kyoto University
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Fujii Toshiyuki
Research Reactor Institute, Kyoto University
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FUJII Toshiyuki
Research Laboratories, Fujisawa Pharmaceutical Co., Ltd.
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NAKASHIMA Takuji
Kitasato Research Organization for Infection Control Sciences, Kitasato University
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NAGAI Takayuki
Nuclear Fuel Cycle Engineering Lab., Japan Atomic Energy Agency
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