Mass Spectrometric Investigation of Structures of Intermediates in Acridine Chemiluminescence
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概要
- 論文の詳細を見る
Liquid secondary ionization mass spectra (LSIMS) of methylsulfate salts of phenyl, isopropyl, and methyl 10-methyl-acridinium-9-carboxylate were examined under chemiluminescent conditions. Under chemiluminescence conditions, oxygenated acrydinium ions [M + 16]+ were observed, whose structures were elucidated as 9-oxy derivatives on the basis of their fragmentation processes obtained by linked scanning at constant B/E. The oxygenated ions are probably derived from the mass spectrometric reaction of the hydroperoxy intermediates in the chemiluminescence proposed by McCapra.
- 日本質量分析学会の論文
- 1996-04-20
著者
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HIRANO Takashi
Department of Applied Physics and Chemistry, The University of Electro-Communications
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Ohashi Mamoru
Department Of Applied Physics And Chemistry The University Of Electro-communications
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MATSUNO Tatsuki
Department of Applied Physics and Chemistry, The University of Electro-Communications
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Matsuno Tatsuki
Department Of Applied Physics And Chemistry The University Of Electro-communications
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Hirano Takashi
Department Of Applied Physics And Chemistry The University Of Electro-communications
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