遷移金属触媒を用いたC-H活性化を機軸とする直接ホウ素化およびケイ素化反応

概要

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Direct borylation and silylation of unreactive C-H bonds catalyzed by transition metal complexes have been extensively studied by several research groups and have become economical, efficient, elegant, and environmentally benign protocols for the synthesis of a variety of organoboron and organosilicon compounds. A number of transition metal complexes catalyzes C-H borylation and silylation of alkanes, arenes, heteroarenes, alkenes, or benzylic positions of alkylarenes by diborons or hydoroboranes and disilanes or hydrosilanes to produce the corresponding alkyl-, aryl-, heteroaryl-, vinyl-, or benzylboron and -silicon compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation and silylation of hydrocarbons based on C-H activation are summarized.
社団法人　有機合成化学協会　(The Society of Synthetic Organic Chemistry, Japan)の論文
2005-05-01