Tensile Properties of TiAl Based Alloy in a Gaseous Hydrogen Atmosphere in a Temperature Range from Room Temperature to 973K

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Ti-48Al-2Cr-2Nb (at%) with a γ structure was tensile-tested in a high purity hydrogen gas in a temperature range of room temperature to 973 K. The reduction of elongation was observed in hydrogen gas in the entire temperature range, although the fracture surface changed mainly from cleavage to grain boundary facets both in vacuum and in hydrogen gas as the temperature increases. From transmission electron microscopy, fractography, the content of hydrogen introduced during tensile testing, and consideration of the diffusion rate of hydrogen, the hydrogen environmental embrittlement of the TiAl based alloy is suggested to result not from the formation of hydrides but from local accumulation of solute hydrogen introduced by dislocations from the test environment during testing. The hydrogen introduced during tensile deformation mainly decreases not grain boundary strength but cleavage strength, and then the reduction of elongation in hydrogen gas is caused by the decrease of the transgranular strength in the wide temperature range, although the grain boundary strength may also decrease with increasing temperature.
社団法人日本鉄鋼協会の論文
2003-04-15