Comparative Enantioseparation of Monoterpenes by HPLC on Three Kinds of Chiral Stationary Phases with an On-Line Optical Rotatory Dispersion under Reverse Phase Mode
スポンサーリンク
概要
- 論文の詳細を見る
HPLC enantioseparation of chiral monoterpenes was studied using amylose (AD-H), cellulose (OD-H) and β-cyclodextrin (CD-Ph), phenyl carbamate derivatives as chiral stationary phases (CSPs). The contributions of various functional groups of the chiral monoterpenes in capacity factor (k), separation factor (α) and resolution factor (Rs) were investigated. AD-H column clearly showed the chiral recognition in 7 chemicals from a total of 9 analytes and especially for linalool, while the CD-Ph column could achieve efficient enantioseparation on carvone. The enantioseparation mechanism between the analytes and the CSPs is discussed. Chiral HPLC system coupled with ORD detector could be applied to isolate and directly determine the configuration of (3S)-(+)-linalool, which is not commercially available. Moreover, 100% enantiomeric excess of the isolated (3S)-(+)-linalool was observed from the SPME-GCMS result. Additionally, enantioseparation of (3S)-(+)-linalool by preparative HPLC system offered a 500-fold higher sample loading capacity than that of GC.
- 社団法人 日本食品科学工学会の論文
- 2002-11-01
著者
-
TAMURA Hirotoshi
Department of Biochemistry and Food Science, Kagawa Universitry
-
MOOKDASANIT Juta
Department of Biochemistry and Food Science, Kagawa Universitry
-
Mookdasanit Juta
Department Of Biochemistry And Food Science Faculty Of Agriculture Kagawa University
-
Tamura Hirotoshi
Department Of Biochemistry And Food Science Faculty Of Agriculture Kagawa University
-
Tamura H
Department Of Biochemistry And Food Science Faculty Of Agriculture Kagawa University
関連論文
- Characteristic Aroma Components of the Volatile Oil of Yellow Keaw Mango Fruits Determined by Limited Odor Unit Method
- Antitumor Activity of(10Ε, 12Ζ)-9-Hydroxy-10, 12-Octadecadienoic Acid from Rice Bran
- Production of Phenyl-propanoids from Cultured Callus Tissue of the Leaves of Akachirimen-shiso (Perilla sp.)(Organic Chemistry)
- Comparative Enantioseparation of Monoterpenes by HPLC on Three Kinds of Chiral Stationary Phases with an On-Line Optical Rotatory Dispersion under Reverse Phase Mode
- Volatile Constituents in the Peel Oil of Sudachi (Citrus sudachi)(Food & Nutrition)
- Trace Volatile Components in Essential Oil of Citrus sudachi by Means of Modified Solvent Extraction Method
- The Volatile Constituents in the Peel and Pulp of a Green Thai Mango, Khieo Sawoei Cultivar (Mangifera indica L.)
- Volatile Components of the Essential Oils in the Pulp of Four Yellow Mangoes (Mangifera indica L.) in Thailand
- Seasonal Change of Volatile Compounds of Citrus sudachi during Maturation
- Optical Isomers and Odor Thresholds of Volatile Constituents in Citrus sudachi
- Identification and Quantitative Variation of Anthocyanins Produced by Cultured Callus Tissue of Vitis sp.(Organic Chemistry)
- A New Identification Method for Aliphatic Compounds Using Linear Equations of the GC Retention Index Value(Food & Nutrition)