The Impedance Analysis of Reaction Kinetics at the Interface between Molten Sn-S Alloy and ZnCl_2-NaCl Salt

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概要

• 論文の詳細を見る

• The interfacial reaction between molten Sn–S alloy and ZnCl2-NaCl salt was studied by an A. C. impedance method to clarify the individual kinetic factors concerning the electrode reaction at the interface between the alloy and the salt. The total impedance between Sn–S alloy and ZnCl2–NaCl salt was measured. The results obtained were successfully used to determine the individual kinetic factors on electrode reaction between the alloy and the salt, such as electrolyte resistance <I>R</I>e, double-layer capacitance <I>C</I>d, charge transfer resistance <I>R</I>ct, rate constant of desulfurization reaction <I>k</I>f and so on. When overpotential η equals to –85 mV, these values are as follows: <I>R</I>e=2.93×10–5 Ωm2, <I>R</I>ct=2.47×10–5 Ωm2, <I>C</I>d=1.01 Fm–2, <I>k</I>f=2.1×10–3 s–1.

• 社団法人 日本鉄鋼協会の論文
• 1998-08-15

著者

• WANG Shulan

  Graduate School of Electronic Science and Technology

• Wang S

  Notheastern University

• LI Guangqiang

  Notheastern University

• SUI Zhitong

  Notheastern University

• WANG Shulan

  School of Materials and Metallurgy, Northeastern University

• LI Guangqiang

  School of Materials and Metallurgy, Northeastern University

• SUI Zhitong

  School of Materials and Metallurgy, Northeastern University

• Sui Z

  Notheastern University

• Sui Zhitong

  School Of Materials And Metallurgy Northeastern University

関連論文

• PbSnCaTe Films and PbSnCaTe/PbSnTe Superlattices Prepared by Molecular Beam Epitaxy(Semiconductors)
• The Conductivity and the Crystallization of Perovskite (CaTiO_3) from Ti-bearing Blast Furnace Slag Studied by A. C. Impedance Method
• The Impedance Analysis of Reaction Kinetics at the Interface between Molten Sn-S Alloy and ZnCl_2-NaCl Salt
• Dynamic Oxidation of the Ti-bearing Blast Furnace Slag

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